Ion chromatographic determination of ammonium ion in rain and snow samples.

Ion-chromatographic determination of L-tartrate in urine samples.

We propose using ion chromatography to determine tartrate concentration in urine. A 100-microL sample of urine is diluted and injected into the chromatograph. Tartrate is eluted within 11.5 min as a distinct and well-resolved peak. The sensitivity of the standard procedure (signal-to-noise ratio, 3/1) is 30 mumol/L. The intra-run and interrun coefficients of variation are 2.5% and 4.1%, respect...

EXTRACTION-SPECTROPHOTOMETRIC DETERMINATION OF AMMONIUM ION BY DIBENZO- 18-CROWN-6 AND CALMAGITE

An extraction-spectrophotometric method for the determination of trace amounts of ammonium ion is described. Ammonium ion is effectively extracted as a neutral ternary complex NH . DB 18C6. calmagite at pH 3.0 into chloroform, followed by spectrophotometric determination at =48 5 nm. Molar absorptivity of the ternary complex at this wavelength is 1.08 10 mol cm . Beer's law is obeyed over...

Ion chromatographic determination of inorganic anions in environmental samples of Korea.

Ion Chromatographic Analyses of Sea Waters, Brines and Related Samples

This review focuses on the ion chromatographic methods for the analyses of natural waters with high ionic strength. At the beginning a natural diversity in ionic composition of waters is highlighted and terminology clarified. In continuation a brief overview of other review articles of potential interest is given. A review of ion chromatographic methods is organized in four sections. The first ...

Ion chromatographic determination of borate in aqueous samples together with other common anions

The conversion of boric acid (pKa ≈ 9) in a more acidic complex, using mannitol or sorbitol as ligands, has been exploited to obtain a sensitive and accurate method for the determination of boric acid by ion chromatography. Both separation and detection conditions have been selected on the basis of available thermodynamic data on the relevant equilibria, and then experimentally optimised on a c...